Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2011, Issue 20-21, Pages 3970-3979Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201100465
Keywords
Porphyrinoids; Cycloaddition; Macrocycles; Nitrogen heterocycles
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Funding
- Fundacao para a Ciencia e a Tecnologia [SFRH/BD/61573/2009, SFRH/BPD/34703/2007]
- Fundação para a Ciência e a Tecnologia [SFRH/BD/61573/2009, SFRH/BPD/34703/2007] Funding Source: FCT
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The synthesis of new types of stable 4,5,6,7-tetrahydropyrazolo[1,5-a]pyridine-fused chlorins and bacteriorins through [8 pi+2 pi] cycloaddition of diazafulvenium methides with porphyrins and chlorins is reported. Detailed absorption and fluorescence spectral and quantum yield measurements have been made on all new compounds. These show potential for various biomedical applications.
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