Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2012, Issue 1, Pages 58-61Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201101550
Keywords
Fluorine; Alkynes; Copper
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Funding
- National Natural Science Foundation of China [21072028, 20832008]
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An improved method for the efficient copper-mediated trifluoromethylation of terminal alkynes has been developed. This protocol highlights the convenient access to a variety of aryl-substituted trifluoromethylated alkynes by oxidative trifluoromethylation with two equivalents of TMSCF3 at room temperature.
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