Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2011, Issue 25, Pages 4756-4759Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201100785
Keywords
Copper; Selenium; Heterocycles; Cross-coupling; Domino reactions
Categories
Funding
- Department of Science and Technology, New Delhi
- Council of Scientific and Industrial Research, New Delhi
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Domino C-Se cross-coupling of 2-(iodoaryl)selenoureas with aryl iodides has been accomplished in the presence of a copper(I)-1,1-phenanthroline complex at moderate temperature. The reactions involve intra-and intermolecular C-Se cross-coupling to give the substituted 2-(arylselanyl)arylcyanamides. Aryl iodides having electron-donating and -withdrawing substituents are compatible, affording the target selanyl ethers in high yield.
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