Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 18, Pages 3465-3472Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000308
Keywords
Homogeneous catalysis; Cyclization; Diselenides; Isocoumarins
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Funding
- Higher Education Commission of Pakistan
- Ecole Nationale Superieure des Ingenieurs en Arts Chimiques et Technologiques (ENSIACET), France
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Cyclizations of stilbenecarboxylic acids to the corresponding isocoumarin derivatives using diselenide or disulfide reagents have been developed. By employing bis(triflouroacetoxy)iodobenzene as oxidant for the 6-endo-trig cyclizations a variety of dihydroisocoumarins have been prepared in good yields. This method is capable of forming isocoumarins and dihydroisocoumarin derivatives by a cyclization-elimination route.
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