Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 10, Pages 1854-1857Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000060
Keywords
Amination; Cross-coupling; Copper; Nitrogen heterocycles; Water chemistry
Categories
Funding
- Natural Science Foundation of China [20672075, 20771076, 20901052]
- Sichuan Provincial Foundation [08ZQ026-041]
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The cross-coupling reaction between aryl halides and aqueous ammonia was efficiently catalyzed by the sulfonato-Cu(salen) complex in water with high yields. A variety of substituted aryl bromides and aryl iodides were found to be applicable to the environmentally benign system. Substituted 1H-benzimidazole could also be easily prepared by coupling aqueous ammonia
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