Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 16, Pages 2999-3025Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000004
Keywords
Organocatalysis; Transition metals; Asymmetric catalysis; Transition-metal catalysis; Dual catalysis
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Funding
- Direct For Mathematical & Physical Scien [0844602] Funding Source: National Science Foundation
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In the past several years, applications of transition metal complexes in tuning the reactivity of organocatalyst-promoted transformations have attracted increasing attention in the synthetic community. Efforts in this direction have led to the discovery of unprecedented reactivities, which are not accessible through the use of either of these two catalytic systems separately. The concept continues to develop and offers huge potential. This microreview describes and summarizes recent progress in this field, focusing on discussion of the enhancement and diversification of reactivity patterns in organocatalysis through the deployment of transition metal complexes.
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