Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 7, Pages 1227-1230Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200901282
Keywords
Palladium; Alkenylation; Nitrogen heterocycles; Alkenes; C-H functionalization
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Funding
- National Natural Foundation of China [20625205, 20772034, 20932002]
- Guangdong Natural Science Foundation [07118070]
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A palladium-catalyzed alkenylation of 1,2,3-triazoles with terminal conjugated alkenes by direct C-H functionalization has been developed in the presence of Cu(OAC)(2) and di-oxygen. A variety of terminal alkenes such as acrylates and styrenes can perform the direct oxidative coupling reactions with 1,2,3-triazoles to afford the corresponding alkenylated products in 30-90% yield.
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