Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 13, Pages 2457-2460Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000147
Keywords
Synthetic methods; Cross-coupling; Nickel; Boron; Biaryls
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A practical, efficient protocol was developed for the Suzuki reaction of aryl tosylates with arylboronic acids The process was promoted by a nickel-based catalyst system consisting of the easily available Ni-II-(sigma-aryl) complex and the simple ligand PPh3 in toluene in the presence of the base K2CO3, The convenient operation, high yield, generality, and low cost make this method viable for most common laboratories and applicable in large-scale preparations
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