Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 15, Pages 2845-2848Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000141
Keywords
Synthetic methods; Indium; Allylation; Nitrogen heterocycles
Categories
Funding
- Direccion General de Investigacion - Ministerio de Ciencia e Innovacion (DGI-MICINN) [CTQ2006-10292, CTQ2009-09318]
- Universidad Complutense-Banco Santander Central Hispano (UCM-BSCH) [GR58/08]
- Comunidad Autonoma de Madrid (CAM) [S2009/PPQ-1752]
- Consejo Superior de Investigaciones Cientificas (CSIC)
- Ministerio de Ciencia e Innovacion (MICINN)
- European Social Fund
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Quaternary 3-amino-2-oxindoles have been obtained via allylation and propargylation reactions of imino-isatins in aqueous media promoted by In and Zn respectively, under Barbier conditions, in good to excellent yields. A quaternary new stereocenter has been formed without hydrolysis of the starting imino-isatin.
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