Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 31, Pages 6097-6102Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000959
Keywords
C-H activation; Palladium; Copper; Nitrogen heterocycles; Alkenes
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Funding
- Centre National de Recherche Scientifique (CNRS)
- Ministere de l'Education Nationale de la Recherche et de la Technologie (MENRT)
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Direct alkenylation of azole heterocycles through Pd-Cu-catalyzed C-H bond activation has been reported using alkenyl bromides as the coupling partners. The reaction enables the introduction of various mono-, di-, or trisubstituted alkenyl bromides as well as a benzyl chloride to the caffeine core.
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