Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 22, Pages 4306-4311Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000560
Keywords
Quinones; Asymmetric synthesis; Annulation; Cyclization; Natural products
Categories
Funding
- Department of Science and Technology, New Delhi [SR/S1/OC-25/2008]
- Council of Scientific and Industrial Research (CSIR), New Delhi
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A concise asymmetric synthesis of (-)-hongconin and (-)-1-epi-hongconin is described The synthesis features an efficient combination of Dotz benzannulation or lactaldehyde arylation and the oxa-Pictet-Spengler reaction as the key steps The synthesis is completed in 10-11 steps from the chiral pool material (R)-methyl lactate
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