Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 22, Pages 4181-4184Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000477
Keywords
Sulfonimides; Bronsted acids; Chirality; Organocatalysis
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Funding
- Hong Kong Baptist University [FRG/08-09/II-45]
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A general approach to the synthesis of optically pure 3,3'-diaryl chiral sulfonimides (CSIs) from racemic BINOL has been developed ortho-Lithiation is directed by the sulfonyl groups, and the resulting dihalides serve as the common precursors for the aryl-substituted CSIs.
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