4.5 Review

One-Pot Syntheses of α,β-Unsaturated Carbonyl Compounds through Palladium-Mediated Dehydrogenation of Ketones, Aldehydes, Esters, Lactones and Amides

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 20, Pages 3779-3790

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000278

Keywords

Palladium; Dehydrogenation; Ketones; Aldehydes; Esters; Lactones; Amides

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This review highlights the different direct stoichiometric and catalytic palladium procedures leading to alpha,beta-unsaturated carbonyl compounds from the corresponding ketones, aidehydes, esters, lactones and amides. The proposed mechanisms are described, in some cases with,personal observations.

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