Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 28, Pages 5454-5459Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000765
Keywords
Gold; C-C bond activation; Methylenecyclopropanes
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Funding
- Shanghai Municipal Committee of Science and Technology [08dj1400100-2]
- National Basic Research Program of China [973-2009CB825300]
- National Natural Science Foundation of China [20872162, 20672127, 20821002, 20732008]
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Gold(I) can catalyze the diacetoxylation of methylenecyclopropanes to produce the corresponding diacetoxylated products in moderate to good yields in acetic acid in the presence of iodosobenzene diacetate via C-C bond breaking under mild condition.
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