Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 2, Pages 311-316Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200901010
Keywords
Allenes; Cycloisomerization; Gold; Homogeneous catalysis; Oxygen heterocycles
Categories
Funding
- Deutsche Forschungsgemeinschaft (DFG)
- European Community
Ask authors/readers for more resources
The stereoselective gold-catalyzed 6-endo cyclization. of various beta-hydroxyallenes in the presence of N-iodosuccinimide affords iodinated dihydropyrans in good yield. Subsequent functionalization by palladium-catalyzed cross coupling opens an access to alpha-hydroxyallenes that are converted in a second gold-catalyzed cyclization into furopyrans which occur in various natural products.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
