Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 34, Pages 6539-6543Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201001157
Keywords
Cycloaddition; 1,7-Dipoles; Porphyrin; Chlorin; Bacteriochlorin
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Funding
- Fundacao para a Ciencia e a Tecnologia [PTDC/QUI/64470/2006, SFRH/BD/61573/2009]
- COMPETE
- QREN
- Fundo Europeu de Desenvolvimento Regional
- Fundação para a Ciência e a Tecnologia [SFRH/BD/61573/2009, PTDC/QUI/64470/2006] Funding Source: FCT
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New and unprecedented [8 pi+2 pi] cycloaddition of diazafulvenium methides with porphyrins and chlorins is reported. The synthetic methodology allowed the access to a new type of 4,5,6,7-tetrahydropyrazolo[1,5-alpha]pyridine-fused chlorins and bacteriorins in a selective fashion.
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