4.5 Article

InIII-Catalysed Tandem C-C and C-O Bond Formation between Phenols and Allylic Acetates

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 32, Pages 6239-6248

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000738

Keywords

Indium; Lewis acids; Allylation; Oxygen heterocycles; Tandem reactions

Funding

  1. French Agence National de la Recherche [ANR-07-CP2D-04-01]

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Indium trif late catalysed tandem allylation-intramolecular hydroalkoxylation was efficiently carried out by using 1 mol% of the catalyst under mild conditions to afford the dihydrobenzopyran ring system (chroman-type structure) in good yields. Kinetic, mechanistic and theoretical studies are also presented.

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