Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 35, Pages 6719-6721Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201001083
Keywords
Aromatic substitution; Substituent effects; Synthetic methods; Arenes; Diazo compounds
Categories
Funding
- Union Tool Scholarship Foundation
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The intermolecular aromatic substitution of N,N-disubstituted anilines with diazo esters is achieved under mild conditions in the presence of a catalytic amount of copper(II) triflate (up to 89% yield). The scope and limitations regarding substrates, diazo esters, and ligands in this reaction are described.
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