Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 8, Pages 1574-1578Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200900817
Keywords
Amines; Nitriles; Nucleophilic addition; Grignard reagents
Categories
Funding
- KAdemCustomChem GmbH
- Land Niedersachsen
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Various 1-substituted cyclopentylamines (25 examples, 10-89% yield) have been prepared according to a one-pot procedure by the addition of tetramethylenebismagnesium di-bromide in the presence of Ti(OiPr)(4) to aliphatic, aromatic and heteroaromatic nitriles, respectively.
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