Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2010, Issue 10, Pages 1951-1970Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200901481
Keywords
Carbohydrates; Pseudodisaccharides; Glycosides; Glycomimetics; Lectins; Sulfur
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Funding
- Swedish Research council (Vetenskapsradet)
- Carl Tryggers Stiftelse
- Stockholm University
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Hydrolytically stable non-glycosidically linked tail-to-tail pseudodisaccharides are linked by a single bridging atom remote from the anomeric centre of the constituent monosaccharides. Some such pseudodisaccharides with sulfur or oxygen bridges were found to act as disaccharide mimetics in their binding to the Banana Lectin and to Concanavalin A. A versatile synthetic route to a small library of such compounds is described.
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