Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2009, Issue 5, Pages 666-672Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200800976
Keywords
Molybdenum; Nucleophilic substitution; Allylic compounds; Alcohols
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Funding
- National Natural Science Foundation of China [20672053, 20832001]
- National Basic Research Program of China [2007CB925103]
- Program for New Century Excellent Talents in the University of China [NCET-06-0425]
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Direct nucleophilic substitution of allylic alcohols with various nitrogen, oxygen, and carbon nucleophiles catalyzed by MoO2(acac)(2) was realized. The corresponding products were obtained in moderate-to-excellent yields. Studies of the reaction mechanism showed that a carbenium intermediate was formed in the transition state. ( (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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