Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2009, Issue 33, Pages 5804-5809Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200900944
Keywords
Organocatalysis; Amination; Alkaloids; Asymmetric catalysis
Categories
Funding
- Sichuan University
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An efficient procedure for the asymmetric allylic animation of Morita-Baylis-Hillman carbonates with cyclic imides catalysed by commercially available cinchona alkaloids is reported, It proves to be a facile protocol that affords alpha-methylene beta-amino esters with good-to-excellent enantioselbctivities (up to 94 % ee) and in high yields (up to 97%). ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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