Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2009, Issue 8, Pages 1144-1147Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200801176
Keywords
Iron; Esterification; Aldehydes; Homogeneous catalysis; Oxidation
Categories
Funding
- CNRS
- Ministere de l'Enseignement Superieur et de la Recherche
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A highly efficient, mild, and simple protocol for Fe(ClO4)(3)center dot xH(2)O-catalyzed oxidative esterification of aldehydes was developed. Several aromatic and aliphatic aldehydes reacted with simple primary and secondary alcohols, used as the solvent, smoothly in the presence of an iron salt catalyst (10 mol-%) and hydroperoxide (4 equiv.) as an oxidant to generate the corresponding esters in good to excellent yields. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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