Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2009, Issue 32, Pages 5509-5512Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200900894
Keywords
Synthetic methods; Cyclization; Heterocycles; Platinum; Selenium
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Funding
- Japan Society for Promotion in Science (JSPS)
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Alkyl ortho-alkynylphenyl selenides 1 were efficiently converted into 2,3-disubstitiited benzo[b]selenophenes 2 in the presence of a catalytic amount of PtCl2. The reactions were shown to proceed via carboselenation, specifically the addition of a C-Se bond to the alkynes. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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