Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2009, Issue 24, Pages 4051-4058Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200900323
Keywords
DNA; Mismatch; Azobenzenes; Photoswitch; Nanostructures; Ligand design
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Funding
- Japan Society for the Promotion of Science [18105006]
- Grants-in-Aid for Scientific Research [18105006] Funding Source: KAKEN
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Photoswitchable DNA-binding ligands should be useful for controlling diverse biological functions involving DNA and reversible assembly of DNA-based nanostructures. In work directed towards the development of photoswitchable ligands with various sequence specificities, we have elaborated an efficient synthesis of photoswitchable unsymmetrical ligands possessing pairs of different base recognition elements, A novel photoswitchable ligand incorporating an acylated aminonaphthyridine and an azaquinolone as its base recognition elements can bind to the CAG/CAG sequence in response to light stimuli. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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