Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2009, Issue 23, Pages 3895-3905Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200900332
Keywords
Cyclic voltammetry; Fluorescence; Heterocycles; Mesoporous materials; Radical ions
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Funding
- Deutsche Forschungsgemeinschaft (DFG) [SPP 1181]
- Fonds der Chemischen Industrie
- Consiliul National al Cercetarii Stiintifice din Invatamantul Superior (CNCSIS) [1315]
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Mesoporous hybrid materials of (oligo)phenothiazines covalently grafted onto MCM-41 or SBA-15 silica have been readily prepared from (oligo)phenothiazinyl carbamates. The phenothiazine precursors show interesting electronic properties according to electronic spectroscopy and cyclic voltammetry. The resulting electronically active hybrid materials display fluorescence and can be oxidized to give stable radical-cationic species upon mild oxidation. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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