4.5 Article

Intermolecular hydrogen-bonding pattern of a glycosyl donor: The key to understanding the outcome of sialylation

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2008, Issue 19, Pages 3251-3255

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200800324

Keywords

amides; glycosylation; hydrogen bonds; reactivity; sialic acids

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Changes in the hydrogen-bonding pattern in solutions of glycosyl donor induced by the addition of external amides/imides or by concentration changes influence the yield and stereoselectivity of sialylation. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).

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