Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2008, Issue 27, Pages 4615-4621Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200800481
Keywords
cyclitols; epoxidation; nucleophilic addition; ring expansion; Lewis acids
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Funding
- Department of Chemistry and Ataturk University
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New beta-hydroxy nitrates have been synthesized by the ring-opening reaction of epoxides with Bi(NO3)(3)center dot 5H(2)O, which was used both as a catalyst and reagent. The synthesized molecules are both potential cyclitol mimetics and vasodilators as a result of their hydroxy groups and nitrate esters. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
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