4.5 Article

Synthesis of new β-hydroxy nitrate esters as potential glycomimetics or vasodilators

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2008, Issue 27, Pages 4615-4621

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200800481

Keywords

cyclitols; epoxidation; nucleophilic addition; ring expansion; Lewis acids

Funding

  1. Department of Chemistry and Ataturk University

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New beta-hydroxy nitrates have been synthesized by the ring-opening reaction of epoxides with Bi(NO3)(3)center dot 5H(2)O, which was used both as a catalyst and reagent. The synthesized molecules are both potential cyclitol mimetics and vasodilators as a result of their hydroxy groups and nitrate esters. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).

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