Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2008, Issue 23, Pages 3928-3932Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200800142
Keywords
supported catalysts; green chemistry; nitro compounds
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Funding
- Ministero dell'Universit e della Ricerca (MiUR)
- Universita degli Studi di Perugia [COFIN 2006]
- ADP grant
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We have reported that Amberlite IRA900F (Amb-F) is an efficient metal-free catalyst for the activation of Si-N and Si-O bonds and a mild base in a variety of organic transformations under solvent-free conditions, such as the addition of TMSN3 to (E)-2-aryl-1-cyano-1-nitroethenes, nitriles, alpha,beta-unsaturated acids and their esters, and the addition of dimethylsilyl ketene acetal and ethyl nitroacetate to beta-nitro styrenes. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
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