Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2008, Issue 34, Pages 5723-5730Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200800728
Keywords
Click chemistry; Cycloaddition; Cyclodextrins
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Funding
- Centre National de la Recherche Scientifique (CNRS)
- Agence Nationale de la Recherche [ANR-07-CP2D-05-02]
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A great variety of mono- and polytopic beta-cyclodextrin hosts have been easily synthesized by Using the Cu-I-catalyzed azide-alkyne cycloaddition reaction. Of particular interest for their multibinding properties, dimeric and trimeric CD compounds were obtained by clicking mono-6-azido-beta-cyclo-dextrin derivatives with flexible or rigid dialkynyl spacers. The reaction is general, high-yielding for some of the synthesized molecules (>80%) and proceeds under mild conditions. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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