4.5 Article

Synthesis of Isoxazolopyridobicyclooxacalix[4]arenes: A New Family of Heteracalixarene Systems

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2008, Issue 32, Pages 5407-5413

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200800714

Keywords

Calixarenes; Cage Compounds; Density functional calculations; X-ray diffraction

Funding

  1. University of Siena

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A new family of isoxazolopyridobicyclooxacalix[4]arenes was obtained by reaction of dichloroisoxazolopyridines with phloroglucinol. X-ray crystallography and density functional calculations were used for their structural determination and evaluation of their chemical properties. Their role as metal chelators was studied by mass spectrometry. This new family of heteracalixarenes is of potential interest for host-guest interactions. ( (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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