Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2008, Issue 29, Pages 4999-5004Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200800624
Keywords
Phosphotungstic acid; Benzylation; Alcohols; beta-Dicarbonyl compounds; Atom-economical reactions
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Funding
- National Natural Science Foundation of China [20621061, 20772117]
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12-Phosphotungstic acid was used as an efficient, ecofriendly, and air- and moisture-stable catalyst to promote the direct substitution of the hydroxy group of benzylic and atlylic alcohols with various P-dicarbonyl compounds. This powerful protocol for carbon-carbon bond-forming reactions provides monoalkylated dicarbonyl compounds in high yields with great efficiency. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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