Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2008, Issue 7, Pages 1265-1270Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200700645
Keywords
gorgonians; nitrogen heterocycles; hicksoanes A-C; natural products
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Novel eight-membered heterocycles, named hicksoanes AC, were isolated from the gorgonian Subergorgia hicksoni. Their structures, including the absolute configuration of all three stereocenters, were determined by means of extensive spectroscopic data, Hicksoanes have a unique structure containing a triazocane cycle, which is substituted by isoleucine and tryptophan moieties. Hicksoanes A-C showed antifeeding activity against goldfish at natural concentration (10 mu gmL(-1)).
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