Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2008, Issue 3, Pages 485-491Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200700772
Keywords
multicomponent reactions; palladium; oxabenzonorbornadiene; alkynes
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A three-component coupling reaction of organic halides with oxabicyclic alkenes and terminal alkynes was catalyzed by a palladium complex and a phase-transfer agent in the presence of aqueous NaOH. The reaction gave a series of 5,6-disubstituated 7-oxabenzonorbornene derivatives in good yields. The disubstituted products from oxabenzonorbornadiene can be readily converted into polyaromatic hydrocarbons by a Lewis acid mediated deoxyaromatization reaction. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
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