Journal
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY
Volume 115, Issue 3, Pages 295-300Publisher
WILEY-BLACKWELL
DOI: 10.1002/ejlt.201100395
Keywords
Critical aggregation concentration; Enthalpy; Entropy; Light scattering; Organogels
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Mixtures of -oryzanol and -sitosterol were used to structure different oils (decane, limonene, sunflower oil, castor oil, and eugenol). The -oryzanol and -sitosterol mixtures self-assemble into double-walled hollow tubules (approximate to 10nm in diameter) in the oil phase, which aggregate to form a network resulting in firm organogels. The self-assembly of the sterol molecules into tubules was studied using light scattering and rheology. By using different oils, the influence of the polarity of the oil on the self-assembly was studied. The effects of temperature and structurant concentration on the tubuler formation process were determined and the thermodynamic theory of self-assembly was applied to calculate the change in Gibbs free energy (G0), enthalpy (H0), and entropy (S0) resulting from the aggregation of the structurants was determined. The self-assembly was found to be enthalpy-driven as characterized by a negative H0 and S0. A decreasing polarity of the oil promotes the self-assembly leading to formation of tubules at higher temperatures and lower structurant concentrations.
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