Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 27, Pages 4434-4449Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201402249
Keywords
Gold; Heterometallic complexes; Stimuli-responsive materials; Luminescence; Gas sorption
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Funding
- MTA (Hungarian Academy of Sciences) through the Lendulet Programme [LP2012-21/2012]
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The role of noncovalent interactions is reviewed in the context of the stimuli-responsive behaviour of gold(I) and gold-heterometal complexes. These noncovalent interactions are often highly sensitive to physical (thermal, optical, electrical, mechanical, etc.) or chemical (solvents, guests, etc.) stimuli, which trigger alterations in molecular and crystal structures that lead to dynamic changes in the macroscopic properties of gold compounds. In this microreview, we have summarized some representative examples of gold(I) complexes that exhibit intriguing stimuli-responsive properties such as thermochromic, mechanochromic, vapochromic and solvatochromic luminescence, as well as vapochromism and gas sorption. Stimuli-responsive functional materials with specific properties have potential uses in various applications including chemical sensors, memory, data storage, security inks and separation technologies.
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