Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume 2013, Issue 26, Pages 4541-4545Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201300634
Keywords
Carbon dioxide fixation; Homogeneous catalysis; Aluminum; Copolymerization; N,O ligands
Categories
Funding
- Helmholtz Research School
- Bundesministeriums fur Bildung und Forschung (BMBF)- [Forderkennzeichen 01RC0901A]
Ask authors/readers for more resources
The coupling reaction of epoxides and CO2 is in the focus of many research activities in academia as well as in the industry. In this contribution we report on a versatile aluminum-based homogeneous catalyst utilizing an easy-to-synthesize N2O2 ligand system in combination with various cocatalysts, all of them producing pure alternating poly(cyclohexene carbonate)s with M-n values in the range 10000-15000 gmol(-1). This system also efficiently catalyzes the formation of propylene carbonate.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available