Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume 2013, Issue 22-23, Pages 3784-3807Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201300223
Keywords
High-valent compounds; O ligands; N ligands; Transition metals; C-H functionalization; O-O bond formation
Categories
Funding
- German funding agency Deutsche Forschungsgemeinschaft (Cluster of Excellence Unifying Concepts in Catalysis) [EXC 314/1]
- Berlin Graduate School of Natural Sciences and Engineering (BIG-NSE)
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This review summarizes the properties of group 9-11 metal-oxo and metal-imido complexes, which have been either isolated or proposed as reactive intermediates in metal-catalyzed organic transformations. We begin with a general description of the bonding of transition-metal-oxo and -imido complexes in various geometries, followed by a discussion of complexes from groups 9-11. The focus of this review is to provide a clear picture of the state of the art as well as insight towards potential future synthetic endeavors.
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