Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume 2013, Issue 34, Pages 5821-5825Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201301164
Keywords
Coordination modes; N ligands; Silicon; Silylenes
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Funding
- Deutsche Forschungsgemeinschaft [TA 75/16-1]
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The first donor-stabilized silylenes with guanidinato ligands, compounds 4 and 6, were synthesized and structurally characterized in the solid state and in solution. As demonstrated by single-crystal X-ray diffraction studies, compound 4 contains a bidentate and a monodentate guanidinato ligand of the type [iPrNC(NiPr2)NiPr](-), and compound 6 contains the bidentate guanidinato ligand [ArNC(NMe2)NAr](-) (Ar = 2,6-diisopropylphenyl) and the monodentate amido ligand [(Me3Si)(2)N](-). Both silicon(II) complexes exist also in solution.
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