Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume 2013, Issue 30, Pages 5222-5232Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201300729
Keywords
Supramolecular chemistry; Self-assembly; Ruthenium; Antitumor agents; Biological activity
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Funding
- University of Ulsan
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The coordination-driven self-assembly of N-donor ligands with dinuclear arene-ruthenium building blocks has allowed the construction of a wide range of cationic supramolecules with different architectures and functionalities. These supramolecules include (1) hexacationic molecular metallaprisms in which the size of the cycle and type of the arene-ruthenium acceptor and organic linker influence the antitumor behavior of the resulting self-assembly, and (2) tetracationic molecular metallarectangles, which have host-guest capabilities and allow sensing of biological properties. This report covers the synthetic and structural aspects of these coordination-driven self-assembled supramolecules as well as their most promising applications, with a particular focus on potential biological, sensing, and host-guest applications.
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