Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 33, Pages 5456-5460Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201201021
Keywords
Selenium; Conformation analysis; X-ray diffraction; NMR spectroscopy; Quantum chemistry
Categories
Funding
- Russian Foundation for Basic Research [10-03-00505, 10-03-01115]
- Russian Academy of Sciences
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The structures of two new T-shaped selenyl chloride adducts studied by experimental (multinuclear NMR, IR, and Raman spectroscopy and X-ray diffraction analysis) and theoretical (ab initio and DFT quantum chemical calculations) methods clearly demonstrate the possibility of propeller-like free rotation of the SeCl2 moiety around the CSe bond and indicate the absence of any significant double-bond character.
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