Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 1, Pages 54-60Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201200966
Keywords
Homogeneous catalysis; Ruthenium; Ligand design; Metathesis; Membranes
Categories
Funding
- Agence Nationale de la Recherche (ANR) [ANR-09-CP2D-11-01]
Ask authors/readers for more resources
A series of four ruthenium-based olefin metathesis catalysts has been prepared. These new complexes were designed with nanofiltration in organic media in mind; steric enlargement and functionalisation by means of polar ethylene glycol chains were incorporated. New complexes based on the stable 2nd generation Hoveyda-type architecture and featuring substitution either on the NHC backbone or on the N-aryl substituent of the NHC have been prepared and fully characterized. The application of these complexes in a series of olefin metathesis transformations revealed that these modified catalysts retained activity on par with the parent Hoveyda catalyst thus validating the disclosed ligand design.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available