Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 18, Pages 3023-3031Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201200183
Keywords
Calcium; Strontium; Alkaline earth metals; Ring-opening polymeri-zation; Oxidation
Categories
Funding
- European Research Council [FP7-People-2010-IIF ChemCatSusDe]
- Centre National de la Recherche Scientifique (CNRS)
- Institut Universitaire de France
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Well-defined (beta-diketiminate)calcium and -strontium cationic complexes paired with weakly coordinating anions have been prepared in high yields by straightforward protocols. These highly electrophilic species are efficient catalysts for the immortal ring-opening polymerization of lactide and display unusual reactivity by providing a unique example of oxidation of a {BDIiPr} core to give a diiminoalkoxide.
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