Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 20, Pages 3263-3265Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201200456
Keywords
Phosphinidene; P ligands; Tungsten; Synthesis design; Metathesis
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Funding
- Polish Ministry of Science and Higher Education [N N204 271535]
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Metathesis reactions between diimido complexes of tungsten(VI) [(ArN)2WCl2] (Ar = 2,6-iPr2C6H3) and lithium derivatives of diphosphanes R2PP(SiMe3)Li (R = tBu and iPr) yield two anionic diimido complexes of tungsten with side-on bonded phosphanylphosphinidene ligands, [(ArN)2WCl(?2-R2PP)]. Both complexes are structurally characterized. A possible reaction mechanism and the role of donor solvents are discussed on the basis of NMR spectroscopic results.
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