Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 27, Pages 4259-4263Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201200632
Keywords
Enzyme models; Electrochemistry; Iron; Proton reduction; Electron transfer
Categories
Funding
- Shenzhen Government [JC201005260103A]
- Swedish Research Council
- K&A Wallenberg Foundation
- Swedish Energy Agency
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A Fe3S4 complex bridged by azapropanedithiolate (adt), complex 6, was prepared as a potential model of the HOXair state of [FeFe]-hydrogenases. Complex 6 was characterized by IR and 1H NMR spectroscopy, and its structure was determined by X-ray crystallography. The electrochemical studies show that complex 6 is redox-active under acidic conditions, which provides insight into the catalytic mechanism. Hydrogen evolution, driven by visible light, was observed in CH3CN/D2O solution by online mass spectroscopy.
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