Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 3, Pages 363-375Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201100752
Keywords
Homogeneous catalysis; Cooperative catalysis; First-row metals; Ligand-metal cooperativity; Dinuclear complexes; Noninnocent ligands; Hemilabile ligands
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Funding
- NWO CW VENI Innovative Research [700.56.403]
- NWO-CW
- NWO-ACTS
- NRSC-C
- SmartMix program CATCHBIO
- BioSolarCells consortium
- European Research Council (ERC) [279097]
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Cooperative catalysis with first-row transition metals holds much promise for future developments regarding sustainable, selective transformations, including e. g. alkenes, dienes and a variety of small molecules such as CO2, N-2 and water. This non-exhaustive analysis of the current state-of-the-art aims to give a comprehensive overview of the various design strategies and applications of first-row transition metal cooperative reactivity and to provide leads for new research initiatives in order to expand this emerging field. The main aspects covered involve bimetallic cooperativity, redox-noninnocent ligands in combination with first-row transition metal complexes, otherwise reactive or noninnocent scaffolds that can induce metal-ligand bifunctional substrate activation and the design of adaptive ligands and complexes thereof, wherein hemilability is a key factor for selective reactivity. The metals under review are primarily the late transition metals Fe, Co, Ni and Cu.
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