Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 20, Pages 3031-3042Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201100407
Keywords
Cyanide ligands; Heterometallic complexes; Spin crossover; Electrochemistry; Electron transfer
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Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
- Japan Society for the Promotion of Science (JSPS)
- Grants-in-Aid for Scientific Research [21108006] Funding Source: KAKEN
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Cyanide-bridged molecular squares offer a unique opportunity for study, as they represent a model of the simplest unit of Prussian blue and allow access to a wide range of physical properties that can be monitored, such as rich electrochemistry, valence- and spin-state control, and spin-crossover phenomena. This microreview presents recent findings in the field of cyanide squares with particular focus on their syntheses and physical properties.
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