Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 25, Pages 3761-3767Publisher
WILEY-BLACKWELL
DOI: 10.1002/ejic.201100467
Keywords
Light-induced valence tautomerism; ESR; Cobalt; Charge transfer; Glasses
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Funding
- Japan Society for the Promotion of Science (JSPS), Japan [21350081]
- Grants-in-Aid for Scientific Research [22108525, 21350081] Funding Source: KAKEN
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Light-induced valence tautomerism (LIVT) of a dinuclear complex, [{Co(dpqa)}(2)(dhbq)](PF(6))(3) (1), was investigated by ESR analysis of dhbq(3-). LIVT phenomena were observed in the sample diluted in the glass matrix as well as that in powder form. The signal decay and the relaxation were analyzed by double exponential fitting; the results suggest a two-step mechanism. Quantum mechanical tunneling was clearly observed in the glass matrix.
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