Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 7, Pages 1100-1105Publisher
WILEY-BLACKWELL
DOI: 10.1002/ejic.201000872
Keywords
Enzyme models; Electrochemistry; Iron; Hydrogenases; Cluster compounds
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Funding
- Swedish Research Council
- K&A Wallenberg Foundation
- Swedish Energy Agency
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In the attempted replacement of carbon monoxide by the bis(phosphane) dppv in a dinuclear [2Fe2S] complex, a trinuclear [3Fe2S] complex with two bis(phosphane) ligands was unexpectedly obtained. On protonation, this gave a bridged hydride complex with an unusually low potential for the reduction of protons to molecular hydrogen. The redox potential also appears sufficiently positive for direct electron transfer from an excited [Ru(bpy)(3)](2+) sensitizer.
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