Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 7, Pages 1038-1042Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201000984
Keywords
Iron; Sulfur; Hydrogen; Electrochemistry; Hydrogenases; Bioinspired chemistry
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Funding
- Centre National de la Recherche Scientifique (CNRS)
- Agence Nationale de la Recherche (ANR)
- Universite de Bretagne Occidentale (UBO)
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Six-membered heterocycles, 1,4-dithiane and 1,4-thioxane, were treated with [Fe-2(CO)(6)(mu-pdt)] (pdt = propanedithiolate) in order to synthesise [2Fe3S] complexes with well positioned heteroatoms as potential base. Monosubstituted compounds of general formula [Fe-2(CO)(5)L(mu-pdt)] (L = 1,4-dithiane, 1,4-thioxane) were mainly obtained and characterised by H-1 NMR, IR, elemental analysis and X-ray diffraction studies. Electrochemical behaviour of these monosubstituted derivatives was investigated by cyclic voltammetry. An original tetranuclear cluster with a [4Fe8S] core was also isolated as a minor product and structurally characterised.
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